Synthesis and Reactivity of a Pentacoordinated Thiolate-Based Imido-Alkylidene W(VI) Complexes
Synthesis and Reactivity of a Pentacoordinated Thiolate-Based Imido-Alkylidene W(VI) Complexes
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Paris: EDP Sciences
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English
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Paris: EDP Sciences
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Attempt to synthesize a bis-thiolate tungsten alkylidene catalysts with bulky arenethiolates unexpectedly yielded upon activation of DME a pentacoordinated complex of general formula [W(NAr)(CHCMe3)(SAr’)(κ2-O-CH2-CH2-OMe)], which is active towards self-metathesis of cis-4-nonene compared to the parent bis-benzenethiolate. Des essais dans le but de...
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Synthesis and Reactivity of a Pentacoordinated Thiolate-Based Imido-Alkylidene W(VI) Complexes
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TN_cdi_proquest_journals_2058518144
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_2058518144
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E-ISSN
2804-7699
DOI
10.2516/ogst/2015036
