(E)-Selective Weinreb Amide–type Horner–Wadsworth–Emmons Reaction: Effect of Reaction Conditions, Su...
(E)-Selective Weinreb Amide–type Horner–Wadsworth–Emmons Reaction: Effect of Reaction Conditions, Substrate Scope, Isolation of a Reactive Magnesium Phosphonoenolate, and Applications
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Washington: American Chemical Society
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English
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Washington: American Chemical Society
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An iPrMgCl-deprotonating Weinreb amide–type Horner–Wadsworth–Emmons (HWE) reaction was developed, and the effects of diverse reaction conditions, including the base, cation, solvent, and concentration, were investigated to broaden the substrate scope and achieve high (E)-selectivity. The Weinreb amide–type phosphonoenolate generated from iPrMgCl wa...
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Full title
(E)-Selective Weinreb Amide–type Horner–Wadsworth–Emmons Reaction: Effect of Reaction Conditions, Substrate Scope, Isolation of a Reactive Magnesium Phosphonoenolate, and Applications
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TN_cdi_proquest_journals_3052184509
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_3052184509
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E-ISSN
2573-2293
DOI
10.26434/chemrxiv-2024-wncbr
