H2TPP organocatalysis in mild and highly regioselective ring opening of epoxides to halo alcohols by...
H2TPP organocatalysis in mild and highly regioselective ring opening of epoxides to halo alcohols by means of halogen elements
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Publisher
Switzerland: MDPI AG
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Language
English
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Publisher
Switzerland: MDPI AG
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Contents
We found that elemental iodine and bromine are converted to trihalide nucleophiles (triiodine and tribromide anion, respectively) in the presence of catalytic amounts of meso-tetraphenylporphyrins (H2TPP). Therefore a highly regioselective method for the synthesis of beta-haloalcohols through direct ring opening of epoxides with elemental iodine an...
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Full title
H2TPP organocatalysis in mild and highly regioselective ring opening of epoxides to halo alcohols by means of halogen elements
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TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_6268510
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_6268510
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ISSN
1420-3049
E-ISSN
1420-3049
DOI
10.3390/molecules17055508
