Anionic Polymerization of β -Butyrolactone Initiated with Sodium Phenoxides. The Effect of the Initi...
Anionic Polymerization of β -Butyrolactone Initiated with Sodium Phenoxides. The Effect of the Initiator Basicity/Nucleophilicity on the ROP Mechanism
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Switzerland: MDPI AG
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English
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Switzerland: MDPI AG
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It was shown that selected sodium phenoxide derivatives with different basicity and nucleophilicity, such as sodium
-nitrophenoxide,
-chlorophenoxide, 1-napthoxide, phenoxide and
-methoxyphenoxide, are effective initiators in anionic ring-opening polymerization (AROP) of
-butyrolactone in mild conditions. It was found that phenoxides as...
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Full title
Anionic Polymerization of β -Butyrolactone Initiated with Sodium Phenoxides. The Effect of the Initiator Basicity/Nucleophilicity on the ROP Mechanism
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TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_6680796
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_6680796
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ISSN
2073-4360
E-ISSN
2073-4360
DOI
10.3390/polym11071221
